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If you're using Firefox, Facebook Video Chat also requires installing an add-on which it does automatically although this requires re-starting your browser afterwards.
To start a video chat using Facebook Video Chat, just open a conversation window with a contact and click on the webcam icon.
A message will be sent to the recipient asking them to initiate a webchat.
Facebook Video Chat is a third party plugin for Facebook that allows you to video and audio chat via Facebook.
Video and audio chatting are now possible in Facebook thanks to Skype integration and Facebook Video Chat simply offers an alternative way of doing it.